Glass negatives taken by Bernhardt Otto Holtermann in 1875 to capture the beauty of Sydney Harbour - measuring 1.3 meters wide and weigh around 30kg each are listed on the UNESCO Memory of the World. They are held at the State Library of New South Wales.
Here is the full story http://www.smh.com.au/nsw/140yearold-images-of-sydney-harbour-win-place-in-unescos-memory-of-the-world-registry-20171031-gzbs4u.html
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